To find the electric field using Gauss's law:
\[
\oint \vec{E} \cdot d\vec{A} = \frac{Q}{\varepsilon_0},
\]
where \( Q \) is the total charge enclosed and \( \varepsilon_0 \) is the permittivity of free space.
Step 1: Relate charge to surface charge density.
The total charge \( Q \) on the spherical shell is related to the surface charge density \( \sigma \) and the surface area of the shell (which is \( 4\pi R^2 \)):
\[
Q = \sigma \cdot 4\pi R^2.
\]
Step 2: Simplify the electric field.
By symmetry, the electric field on the surface of the spherical shell is uniform, and the flux through the Gaussian surface (a sphere of radius \( R \)) is:
\[
\oint \vec{E} \cdot d\vec{A} = E \cdot 4\pi R^2,
\]
where \( E \) is the magnitude of the electric field.
Substituting into Gauss's law:
\[
E \cdot 4\pi R^2 = \frac{Q}{\varepsilon_0}.
\]
Substitute the expression for \( Q \):
\[
E \cdot 4\pi R^2 = \frac{\sigma \cdot 4\pi R^2}{\varepsilon_0}.
\]
Canceling \( 4\pi R^2 \) from both sides:
\[
E = \frac{\sigma}{\varepsilon_0}.
\]
Final Answer:
\[
\boxed{\frac{\sigma}{\varepsilon_0}}.
\]