The cause for deviation from Raoult’s law in the colligative properties of non-ideal solutions lies in the nature of interactions at the molecular level. These properties show deviations from Raoult’s law due to difference in interactions between solute–solvent, solute–solute and solvent–solvent. Some liquids on mixing form azeotropes which are binary mixtures having the same composition in liquid and vapour phase and boil at a constant temperature. In such cases, it is not possible to separate the components by fractional distillation. There are two types of azeotropes called minimum boiling azeotrope and maximum boiling azeotrope. (a) Pure ethanol cannot be prepared by fractional distillation of ethanol–water mixture. Comment.
Let $ a_0, a_1, ..., a_{23} $ be real numbers such that $$ \left(1 + \frac{2}{5}x \right)^{23} = \sum_{i=0}^{23} a_i x^i $$ for every real number $ x $. Let $ a_r $ be the largest among the numbers $ a_j $ for $ 0 \leq j \leq 23 $. Then the value of $ r $ is ________.
Let $ y(x) $ be the solution of the differential equation $$ x^2 \frac{dy}{dx} + xy = x^2 + y^2, \quad x > \frac{1}{e}, $$ satisfying $ y(1) = 0 $. Then the value of $ 2 \cdot \frac{(y(e))^2}{y(e^2)} $ is ________.
The left and right compartments of a thermally isolated container of length $L$ are separated by a thermally conducting, movable piston of area $A$. The left and right compartments are filled with $\frac{3}{2}$ and 1 moles of an ideal gas, respectively. In the left compartment the piston is attached by a spring with spring constant $k$ and natural length $\frac{2L}{5}$. In thermodynamic equilibrium, the piston is at a distance $\frac{L}{2}$ from the left and right edges of the container as shown in the figure. Under the above conditions, if the pressure in the right compartment is $P = \frac{kL}{A} \alpha$, then the value of $\alpha$ is ____
Colligative Property of any substance is entirely dependent on the ratio of the number of solute particles to the total number of solvent particles but does not depend on the nature of particles. There are four colligative properties: vapor pressure lowering, boiling point elevation, freezing point depression, and osmotic pressure.
We can notice the colligative properties of arrangements by going through the accompanying examples: