List of practice Questions

The ionization constant of chloroacetic acid is 1.35 × 10–3. What will be the pH of 0.1M acid and its 0.1M sodium salt solution?
Predict if the solutions of the following salts are neutral, acidic or basic: NaCl, KBr, NaCN, NH4NO3, NaNO2 and KF
A 0.02M solution of pyridinium hydrochloride has pH = 3.44. Calculate the ionization constant of pyridine.

Consider two ‘postulates’ given below :

(i) Given any two distinct points A and B, there exists a third point C which is in between A and B. 

(ii) There exist at least three points that are not on the same line. 

Do these postulates contain any undefined terms? Are these postulates consistent? 

Do they follow from Euclid’s postulates? Explain.

The ionization constant of nitrous acid is 4.5 × 10–4. Calculate the pH of 0.04 M sodium nitrite solution and also its degree of hydrolysis.
The pH of 0.1M solution of cyanic acid (HCNO) is 2.34. Calculate the ionization constant of the acid and its degree of ionization in the solution.
The solubility of Sr(OH)2 at 298 K is 19.23 g/L of solution. Calculate the concentrations of strontium and hydroxyl ions and the pH of the solution.
If 0.561 g of KOH is dissolved in water to give 200 mL of solution at 298 K. Calculate the concentrations of potassium, hydrogen and hydroxyl ions. What is its pH?
The pH of milk, black coffee, tomato juice, lemon juice and egg white are 6.8, 5.0, 4.2, 2.2 and 7.8 respectively. Calculate corresponding hydrogen ion concentration in each.
The ionization constant of propanoic acid is 1.32 × 10–5. Calculate the degree of ionization of the acid in its 0.05M solution and also its pH. What will be its degree of ionization if the solution is 0.01M in HCl also?
Why is benzene extra ordinarily stable though it contains three double bonds?
Calculate the hydrogen ion concentration in the following biological fluids whose pH are given below: 
(a) Human muscle-fluid,6.83 
(b) Human stomach fluid,1.2 
(c) Human blood,7.38 
(d) Human saliva,6.4
Write chemical equations for combustion reaction of the following hydrocarbons:
  1. Butane
  2. Pentene
  3. Hexyne
  4. Toluene
Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?
Propanal and pentan-3-one are the ozonolysis products of an alkene? What is the structural formula of the alkene?
An alkene ‘A’ contains three C – C, eight C – H σ bonds and one C – C \(\pi\) bond. ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. Write IUPAC name of ‘A’.
An alkene 'A' on ozonolysis gives a mixture of ethanal and pentan-3-one. Write structure and IUPAC name of 'A'.
Write IUPAC names of the products obtained by the ozonolysis of the following compounds:
  1. Pent-2-ene 
  2. 3,4-Dimethyl-hept-3-ene 
  3. 2-Ethylbut-1-ene
  4. 1-Phenylbut-1-ene
For the following compounds, write structural formulas and IUPAC names for all possible isomers having the number of double or triple bond as indicated: 
  1. C4H8 (one double bond) 
  2. C5H8 (one triple bond)

Which of the following statements are true and which are false? Give reasons for your answers. 

(i) Only one line can pass through a single point. 

(ii) There are an infinite number of lines which pass through two distinct points. 

(iii) A terminated line can be produced indefinitely on both the sides. 

(iv) If two circles are equal, then their radii are equal. 

(v) In Fig., if AB = PQ and PQ = XY, then AB = XY

The ionization constant of dimethylamine is 5.4 × 10–4. Calculate its degree of ionization in its 0.02M solution. What percentage of dimethylamine is ionized if the solution is also 0.1M in NaOH?
Calculate the degree of ionization of 0.05M acetic acid if its pKa value is 4.74. How is the degree of dissociation affected when its solution also contains (a) 0.01M (b) 0.1M in HCl ?
Find the value of k, if x=2, y=1 is a solution of the equation 2x+3y=k.

Check which of the following are solutions of the equation x – 2y = 4 and which are not: 

(i) (0, 2) 

(ii) (2, 0) 

(iii) (4, 0) 

(iv) \((\sqrt 2 , 4 \sqrt2) \)

(v) (1, 1)

What is the pH of 0.001M aniline solution? The ionization constant of aniline can be taken from Table 6.7. Calculate the degree of ionization of aniline in the solution. Also calculate the ionization constant of the conjugate acid of aniline.