One mole of radium has an activity of \( \frac{1}{6.3 \times 10^{37}} \) kilo curie. Its decay constant is:
Step 1: The activity \( A \) of a radioactive substance is given by the formula: \[ A = \lambda N \] where \( \lambda \) is the decay constant and \( N \) is the number of nuclei. For one mole of radium, \( N \) is Avogadro's number (\( N = 6 \times 10^{23} \)).
Step 2: The activity is given as \( A = \frac{1}{6.3 \times 10^{37}} \) kilo curie. We convert this into becquerels (1 kilo curie = \( 3.7 \times 10^{10} \) Bq), so: \[ A = \frac{1}{6.3 \times 10^{37}} \times 3.7 \times 10^{10} = \frac{1}{6.3 \times 10^{34}} \, {Bq} \] Step 3: Now, using the formula for the decay constant: \[ \lambda = \frac{A}{N} = \frac{\frac{1}{6.3 \times 10^{34}}}{6 \times 10^{23}} \approx \frac{1}{6} \times 10^{-10} \, {s}^{-1} \]

Which of the following are ambident nucleophiles?
[A.] CN$^{\,-}$
[B.] CH$_{3}$COO$^{\,-}$
[C.] NO$_{2}^{\,-}$
[D.] CH$_{3}$O$^{\,-}$
[E.] NH$_{3}$
Identify the anomers from the following.

The standard Gibbs free energy change \( \Delta G^\circ \) of a cell reaction is \(-301 { kJ/mol}\). What is \( E^\circ \) in volts?
(Given: \( F = 96500 { C/mol}\), \( n = 2 \))