Step 1: Total number of possible outcomes.
In a standard deck of 52 playing cards,
\[
\text{Total number of outcomes} = 52
\]
Step 2: Number of favourable outcomes for a king.
There are 4 kings in a deck (one from each suit: hearts, diamonds, clubs, spades).
\[
\text{Favourable outcomes for a king} = 4
\]
Step 3: Probability of drawing a king.
\[
P(\text{king}) = \frac{\text{Favourable outcomes}}{\text{Total outcomes}} = \frac{4}{52} = \frac{1}{13}
\]
Step 4: Probability of not drawing a king.
\[
P(\text{not a king}) = 1 - P(\text{king}) = 1 - \frac{1}{13} = \frac{12}{13}
\]
Step 5: Final Answers.
\[
\boxed{P(\text{king}) = \frac{1}{13}, \quad P(\text{not a king}) = \frac{12}{13}}
\]