For cyclic peptides:
• Count unique sequences considering the cyclic structure to avoid duplicates.
• Use the number of amino acids and their combinations to determine possible arrangements.
4
2
1. Cyclic Tripeptides:
- A cyclic tripeptide is a peptide consisting of three amino acids arranged in a cyclic structure without any free ends.
- Given two amino acids, A and B, the tripeptide can have different arrangements depending on the sequence of A and B.
2. Possible Arrangements:
- The cyclic nature of the tripeptide eliminates linear sequence redundancy.
- The distinct arrangements are:
1. A-A-A
2. A-A-B
3. A-B-A
4. A-B-B
Total: 4 unique cyclic tripeptides.
Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R)
Assertion (A): Ketoses give Seliwanoff's test faster than Aldoses
Reason (R): Ketoses undergo -elimination followed by formation of furfural
In the light of the above statements, choose the correct answer from the options given below:
Given below are two statements : one is labelled as Assertion (A) and the other is labelled asReason (R)
Assertion (A): $\alpha$-halocarboxylic acid on reaction with dil $NH _3$ gives good yield of $\alpha$-aminocarboxylic acid whereas the yield of amines is very low when prepared from alkyl halides
Reason (R): Amino acids exist in zwitter ion form in aqueous medium
In the light of the above statements, choose the correct answer from the options given below :