Electron gain enthalpy generally becomes more negative across a period due to increasing nuclear charge but decreases down a group due to increased atomic size.
Electron gain enthalpy is the energy change when an electron is added to an atom in the gaseous state.
- Fluorine (F) has an electron gain enthalpy of \( -328 \) kJ/mol (II).
- Chlorine (Cl) has an electron gain enthalpy of \( -349 \) kJ/mol (IV).
- Oxygen (O) has an electron gain enthalpy of \( -141 \) kJ/mol (I).
- Sulfur (S) has an electron gain enthalpy of \( -200 \) kJ/mol (III).
Thus, the correct matching is:
\[
A \to II, \quad B \to IV, \quad C \to I, \quad D \to III
\]