The elements Na, Mg, Al, and Si all belong to Period 3 of the periodic table.
As we move left to right across a period:
- Atomic number increases
- Effective nuclear charge increases
- Electrons are added to the same shell, so the attraction between the nucleus and outer electrons increases.
Hence, atomic radius decreases across a period.
Order of atomic radius:
\[
\text{Na} > \text{Mg} > \text{Al} > \text{Si}
\]
Answer: Therefore, Si has the smallest atomic radius among the options. Correct answer is option (4).