| LIST-I (Cell) | LIST-II (Use/Property/Reaction) |
|---|---|
| A. Leclanche cell | IV. Reaction at anode Zn → Zn2+ + 2e- |
| B. Ni-Cd cell | III. Rechargeable |
| C. Fuel cell | I. Converts energy of combustion into electrical energy |
| D. Mercury cell | II. Does not involve any ion in solution and is used in hearing aids |
In this question, we need to match the cells listed in List-I with their corresponding uses, properties, or reactions from List-II. Let's analyze each one:
Therefore, the correct answer is A-IV, B-III, C-I, D-II, which matches each cell type from List-I with the correct description or use from List-II.
A. Leclanche Cell: This is a primary cell where the reaction at the anode is: \[ \text{Zn} \rightarrow \text{Zn}^{2+} + 2e^- \] Thus, it matches IV.
B. Ni-Cd Cell: The nickel-cadmium cell is a rechargeable secondary cell commonly used in portable devices. Thus, it matches III.
C. Fuel Cell: Fuel cells convert the energy of combustion (e.g., hydrogen and oxygen) into electrical energy. Thus, it matches I.
D. Mercury Cell: Mercury cells are small, primary cells commonly used in hearing aids, and they do not involve any ion in solution.Thus, it matches II.
Final Match: A-IV, B-III, C-I, D-II.
The molar conductance of an infinitely dilute solution of ammonium chloride was found to be 185 S cm$^{-1}$ mol$^{-1}$ and the ionic conductance of hydroxyl and chloride ions are 170 and 70 S cm$^{-1}$ mol$^{-1}$, respectively. If molar conductance of 0.02 M solution of ammonium hydroxide is 85.5 S cm$^{-1}$ mol$^{-1}$, its degree of dissociation is given by x $\times$ 10$^{-1}$. The value of x is ______. (Nearest integer)
Consider the following half cell reaction $ \text{Cr}_2\text{O}_7^{2-} (\text{aq}) + 6\text{e}^- + 14\text{H}^+ (\text{aq}) \longrightarrow 2\text{Cr}^{3+} (\text{aq}) + 7\text{H}_2\text{O}(1) $
The reaction was conducted with the ratio of $\frac{[\text{Cr}^{3+}]^2}{[\text{Cr}_2\text{O}_7^{2-}]} = 10^{-6}$
The pH value at which the EMF of the half cell will become zero is ____ (nearest integer value)
[Given : standard half cell reduction potential $\text{E}^\circ_{\text{Cr}_2\text{O}_7^{2-}, \text{H}^+/\text{Cr}^{3+}} = 1.33\text{V}, \quad \frac{2.303\text{RT}}{\text{F}} = 0.059\text{V}$
| Concentration of KCl solution (mol/L) | Conductivity at 298.15 K (S cm-1) | Molar Conductivity at 298.15 K (S cm2 mol-1) |
|---|---|---|
| 1.000 | 0.1113 | 111.3 |
| 0.100 | 0.0129 | 129.0 |
| 0.010 | 0.00141 | 141.0 |
