LIST-I (Cell) | LIST-II (Use/Property/Reaction) |
---|---|
A. Leclanche cell | IV. Reaction at anode Zn → Zn2+ + 2e- |
B. Ni-Cd cell | III. Rechargeable |
C. Fuel cell | I. Converts energy of combustion into electrical energy |
D. Mercury cell | II. Does not involve any ion in solution and is used in hearing aids |
A. Leclanche Cell: This is a primary cell where the reaction at the anode is: \[ \text{Zn} \rightarrow \text{Zn}^{2+} + 2e^- \] Thus, it matches IV.
B. Ni-Cd Cell: The nickel-cadmium cell is a rechargeable secondary cell commonly used in portable devices. Thus, it matches III.
C. Fuel Cell: Fuel cells convert the energy of combustion (e.g., hydrogen and oxygen) into electrical energy. Thus, it matches I.
D. Mercury Cell: Mercury cells are small, primary cells commonly used in hearing aids, and they do not involve any ion in solution.Thus, it matches II.
Final Match: A-IV, B-III, C-I, D-II.
For the given cell: \[ {Fe}^{2+}(aq) + {Ag}^+(aq) \to {Fe}^{3+}(aq) + {Ag}(s) \] The standard cell potential of the above reaction is given. The standard reduction potentials are given as: \[ {Ag}^+ + e^- \to {Ag} \quad E^\circ = x \, {V} \] \[ {Fe}^{2+} + 2e^- \to {Fe} \quad E^\circ = y \, {V} \] \[ {Fe}^{3+} + 3e^- \to {Fe} \quad E^\circ = z \, {V} \] The correct answer is: