Question:

Match List I with List II for the oxidation state of central atoms:
List IList II
(A) Cr2O72−(I) +3
(B) MnO4(II) +5
(C) VO3(III) +7
(D) FeF63−(IV) +6
Choose the correct answer from the options given below:

Updated On: Mar 27, 2025
  • (A)- (I), (B)- (II), (C)- (III), (D)- (IV)
  • (A)- (IV), (B)- (III), (C)- (II), (D)- (I)
  • (A)- (I), (B)- (II), (C)- (IV), (D)- (III)
  • (A)- (IV), (B)- (I), (C)- (III), (D)- (II)
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The Correct Option is B

Solution and Explanation

Based on the information given in the image, the correct answer is Option B. Here's a breakdown of the reasoning:

(A) Cr₂O₇²⁻ (Dichromate ion):

  • The oxidation state of Cr in Cr₂O₇²⁻ is +6 (since the overall charge of the ion is -2 and the oxidation states of oxygens are -2).
  • This matches Option II in List II.

(B) MnO₄⁻ (Permanganate ion):

  • The oxidation state of Mn in MnO₄⁻ is +7 (since the overall charge of the ion is -1 and the oxidation states of oxygens are -2).
  • This matches Option III in List II.

(C) VO₃⁻ (Vanadate ion):

  • The oxidation state of V in VO₃⁻ is +5 (since the overall charge of the ion is -1 and the oxidation states of oxygens are -2).
  • This matches Option II in List II.

(D) FeF₆³⁻ (Ferrate ion):

  • The oxidation state of Fe in FeF₆³⁻ is +3 (since the overall charge of the ion is -3 and each fluorine has an oxidation state of -1).
  • This matches Option I in List II.

Thus, the correct matching is Option B:
(A) - (IV), (B) - (III), (C) - (II), (D) - (I).

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