The potential energy of an electric dipole in a uniform electric field is given by:
\[
U = - \vec{p} \cdot \vec{E} = -pE \cos \theta
\]
where:
- \( \vec{p} \) is the dipole moment,
- \( \vec{E} \) is the electric field,
- \( \theta \) is the angle between \( \vec{p} \) and \( \vec{E} \),
- \( p \) is the magnitude of the dipole moment.
From this formula:
1. When the angle \( \theta = 0^\circ \) (i.e., the dipole is aligned with the electric field), the potential energy is minimum, and the work done by the electric field is:
\[
W = pE
\]
2. When the angle \( \theta = 180^\circ \) (i.e., the dipole is opposite to the electric field), the potential energy is maximum negative, and the work done by the electric field is:
\[
W = -pE
\]
3. When the angle \( \theta = 90^\circ \) (i.e., the dipole is perpendicular to the electric field), the potential energy is zero, and no work is done by the electric field.
Thus, the correct matches are:
\[
a \rightarrow i, b \rightarrow ii, c \rightarrow iii
\]