The functional equation $f(x + y) = f(x)f(y)$ implies $f(0) = 1$, as: \[ f(x + 0) = f(x)f(0) \implies f(0) = 1. \] Assume $f(x) = e^{kx}$ (a standard solution for such functional equations). Differentiating both sides of the functional equation: \[ f'(x + y) = f'(x)f(y) + f(x)f'(y). \] At $y = 0$, we get: \[ f'(x) = f'(x)f(0) + f(x)f'(0). \] Given $f'(0) = 2$ and $f(0) = 1$, we find: \[ f'(x) = 2f(x). \] Using the condition $f(5) = 3$, and $f'(x) = 2f(x)$, we calculate: \[ f'(5) = 2f(5) = 2 \cdot 3 = 6. \]