Let A= {−1,0,1,2}, B={−4,−2,0,2} and f,g: A→B be functions defined by \(f(x)=x^2-x, \,x\in A\, and \,g(x)=2\mid\frac{ x-1}{2}\mid-1,x\in A.\). Are f and g equal? Justify your answer. (Hint: One may note that two function \(f:A\to B \,and \: g:A\to B\) such that \(f(a)=g(a) \forall \,a \in\,A,\) are called equal functions).
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.