- The sol formed by \( \text{TiO}_2 \) is negatively charged.
- \( \text{Al}_2\text{O}_3 \cdot x\text{H}_2\text{O} \) can form both positive and negative sols depending on the nature of the conditions, but typically, it forms positive sols.
- Starch forms a negative sol and not a positive one. Therefore, option (3) is incorrect.
Thus, the correct answer is \( \boxed{(3)} \).