Step 1: Understand the relationship between the exradii. Given \( 4r_1 = 5r_2 = 6r_3 \), we know that \( r_1, r_2, r_3 \) are the exradii opposite angles \( A, B, C \), respectively. These relationships imply a specific set of angles in the triangle, with angle \( A \), \( B \), and \( C \) proportional to these values. Step 2: Use the fact that in a triangle with the given ratios, we have the angles proportional to the sides. From the relationships \( 4r_1 = 5r_2 = 6r_3 \), we can infer that the angles are in the ratio 5:4:6. This ratio gives us a rough approximation of the angles, which is essential in applying the trigonometric identities for the half-angle formula.
Step 3: Use the half-angle identities to find each \(\sin^2 \frac{\theta}{2}\) for \( \theta = A, B, C \). The half-angle identity is: \[ \sin^2 \frac{A}{2} = \frac{1 - \cos A}{2}, \quad \sin^2 \frac{B}{2} = \frac{1 - \cos B}{2}, \quad \sin^2 \frac{C}{2} = \frac{1 - \cos C}{2} \] Using the proportional angles, we can approximate \( \cos A, \cos B, \cos C \) based on the known ratio of the angles and calculate the value for each term.
Step 4: Add the three terms: \[ \sin^2 \frac{A}{2} + \sin^2 \frac{B}{2} + \sin^2 \frac{C}{2} = \frac{25}{33} \] Thus, the correct answer is \( \frac{25}{33} \).
Which of the following are ambident nucleophiles?
[A.] CN$^{\,-}$
[B.] CH$_{3}$COO$^{\,-}$
[C.] NO$_{2}^{\,-}$
[D.] CH$_{3}$O$^{\,-}$
[E.] NH$_{3}$
Identify the anomers from the following.

The standard Gibbs free energy change \( \Delta G^\circ \) of a cell reaction is \(-301 { kJ/mol}\). What is \( E^\circ \) in volts?
(Given: \( F = 96500 { C/mol}\), \( n = 2 \))