In a head-on collision of charged particles with a nucleus, the closest approach (\( r \)) is inversely proportional to the energy (\( E \)) of the incoming particle. This is based on the concept of the electrostatic potential energy, where:
\[
E \propto \frac{1}{r}
\]
Thus, if the closest approach for the two alpha particles are \( r_1 = 31.4 \, \text{fm} \) and \( r_2 = 94.2 \, \text{fm} \), the ratio of the energy possessed by the particles \( \alpha_2 \) and \( \alpha_1 \) will be:
\[
\frac{E_2}{E_1} = \frac{r_1}{r_2}
\]
Substitute the given values:
\[
\frac{E_2}{E_1} = \frac{31.4}{94.2} = \frac{1}{3}
\]
Thus, the ratio of the energies possessed by the alpha particles is:
\[
\frac{E_2}{E_1} = 1 : 3
\]