\( \text{M} \xrightarrow{\text{CH}_3\text{MgBr}} \text{N} + \text{CH}_4 \uparrow \xrightarrow{\text{H}^+} \text{CH}_3\text{COCH}_2\text{COCH}_3 \)
The given reaction sequence involves the following steps:
1. Reaction with Grignard Reagent: Compound $M$ reacts with $\text{CH}_3\text{MgBr}$ (a Grignard reagent) to form an intermediate compound $N$. In this step, the Grignard reagent adds to the carbonyl group of $M$, creating a new $\text{C–C}$ bond and releasing $\text{CH}_4$ gas as a by-product. The reaction mechanism involves nucleophilic attack by $\text{CH}_3^-$ on the carbonyl carbon.
2. Hydrolysis: The intermediate $N$ undergoes acid hydrolysis. During this process, the intermediate is converted into $\text{CH}_3\text{COCH}_2\text{COCH}_3$, which is a $\beta$-diketone. Hydrolysis ensures the protonation and stabilization of the newly formed compound.
Key Structural Feature: $\text{CH}_3\text{COCH}_2\text{COCH}_3$ has a $\beta$-diketone structure, where two keto groups are separated by a $\text{CH}_2$ group. This confirms that compound $M$ must also be a $\beta$-diketone precursor.
Among the options provided, only $\text{CH}_3\text{COCH}_2\text{COCH}_3$ matches the final product structure.
Thus, the correct answer is Option 1.
The reaction sequence indicates that compound 'M' reacts with CH3MgBr to produce methane (CH4), suggesting the presence of an acidic hydrogen. The subsequent acidic workup leads to acetylacetone (CH3COCH2COCH3).
Option Analysis:
Conclusion:
The reaction sequence and the final product (acetylacetone) are inconsistent with the given options. The most likely scenario that yields methane is Option 3. However, none of the options directly result in acetylacetone.
There is an error with the given problem. If the final product was an alcohol, then option 3 would be the correct answer. The question as asked contains an error.
Identify the structure of the final product (D) in the following sequence of the reactions :
Total number of $ sp^2 $ hybridised carbon atoms in product D is _____.
Given below are two statements :
In the light of the above statements, choose the most appropriate answer from the options given below :
The number of optically active products obtained from the complete ozonolysis of the given compound is :