Step 1: Klinefelter Syndrome Overview.
Klinefelter syndrome is a genetic condition that affects males, where they have one extra X chromosome. The typical male karyotype is XY, but individuals with Klinefelter syndrome have XXY.
Step 2: Conclusion.
Thus, the correct number of sex chromosomes in Klinefelter syndrome is XXY.
Final Answer:
\[
\boxed{\text{XXY sex chromosomes in Klinefelter syndrome.}}
\]