The volume of each cube is 64 cm\(^3\), so the side length of each cube is:
\[
\text{Side length of cube} = \sqrt[3]{64} = 4 \, \text{cm}
\]
When two cubes are joined end to end, the resulting cuboid will have dimensions:
\[
\text{Length} = 8 \, \text{cm}, \quad \text{Width} = 4 \, \text{cm}, \quad \text{Height} = 4 \, \text{cm}
\]
The surface area of a cuboid is given by the formula:
\[
\text{Surface Area} = 2(lw + lh + wh)
\]
Substituting the values:
\[
\text{Surface Area} = 2(8 \times 4 + 8 \times 4 + 4 \times 4) = 2(32 + 32 + 16) = 2 \times 80 = 160 \, \text{cm}^2
\]
Thus, the correct answer is option (2).