If the equation of the circle whose radius is 3 units and which touches internally the circle $$ x^2 + y^2 - 4x - 6y - 12 = 0 $$ at the point $(-1, -1)$ is $$ x^2 + y^2 + px + qy + r = 0, $$ then $p + q - r$ is:
Step 1: Finding the center and radius of the given circle The given circle equation: \[ x^2 + y^2 - 4x - 6y - 12 = 0 \] Rewriting in standard form, complete the square: \[ (x - 2)^2 - 4 + (y - 3)^2 - 9 - 12 = 0 \] \[ (x - 2)^2 + (y - 3)^2 = 25 \] Thus, the center is \( (2,3) \) and radius \( R = 5 \).
Step 2: Finding the required circle The required circle has radius \( r = 3 \) and is internally tangent at \( (-1,-1) \). Using the equation transformation method and substituting \( (-1,-1) \), we determine \( p, q, r \). After calculation, \[ p + q - r = 2. \]
Which of the following are ambident nucleophiles?
[A.] CN$^{\,-}$
[B.] CH$_{3}$COO$^{\,-}$
[C.] NO$_{2}^{\,-}$
[D.] CH$_{3}$O$^{\,-}$
[E.] NH$_{3}$
Identify the anomers from the following.

The standard Gibbs free energy change \( \Delta G^\circ \) of a cell reaction is \(-301 { kJ/mol}\). What is \( E^\circ \) in volts?
(Given: \( F = 96500 { C/mol}\), \( n = 2 \))