If the energy gap of a substance is 5.4 eV, then the substance is:
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Materials with an energy gap greater than about 3 eV are generally classified as insulators because their large band gap does not allow electrons to easily jump from the valence to the conduction band under normal conditions.
The energy gap of a material determines its conductivity. A gap of 5.4 eV is characteristic of insulators, which have wide energy gaps preventing free electrons from easily jumping the gap to conduct electricity.