Step 1: Equation of the circle.
The given equation of the circle is:
\[
x^2 + y^2 - 2x - 2y - 1 = 0.
\]
We complete the square for both \(x\) and \(y\) terms to write the equation in standard form:
\[
(x-1)^2 + (y-1)^2 = 3.
\]
Thus, the center of the circle is \((1, 1)\) and the radius is \(\sqrt{3}\).
Step 2: Equation of the chord \(PQ\).
The points \(P\left( \frac{\pi}{4} \right)\) and \(Q\left( \frac{\pi}{3} \right)\) lie on the circle, and the slope of the chord \(PQ\) is the difference in their \(y\)-coordinates divided by the difference in their \(x\)-coordinates. Hence, the slope of the chord \(PQ\) is:
\[
\text{slope of } PQ = \frac{y_2 - y_1}{x_2 - x_1} = \frac{\sin \left( \frac{\pi}{3} \right) - \sin \left( \frac{\pi}{4} \right)}{\cos \left( \frac{\pi}{3} \right) - \cos \left( \frac{\pi}{4} \right)}.
\]
After substituting the trigonometric values for the angles \(\frac{\pi}{4}\) and \(\frac{\pi}{3}\), we simplify to find the slope of the tangent that is parallel to this chord.
\[
\boxed{2 + \sqrt{2} - \sqrt{3} - \sqrt{6}}.
\]