Step 1: Equation of the line.
We are given the equation \( kx^2 + xy - y^2 = 0 \). This can be rearranged as:
\[
y = \frac{kx^2}{x - y}
\]
To find the value of \( k \), we use the condition that the line bisects the angle between the co-ordinate axes.
Step 2: Condition for angle bisector.
The condition for a line to bisect the angle between the axes is that the slope of the line is equal to the tangent of half the angle between the axes. For the co-ordinate axes, this angle is \( 45^\circ \), so the slope is 1.
Using this condition and solving the equation, we get the values of \( k \) as \( 0 \) and \( 2 \).
Step 3: Conclusion.
Thus, the values of \( k \) are \( \boxed{0, 2} \).