Step 1: Use formula for angle between pair of lines from a point to a line.
Angle $\theta$ between two lines drawn from point $P$ to a line at perpendicular distance $d$ is given by
\[
\sin\frac{\theta}{2}=\frac{d}{\text{distance from point to line}}
\]
Step 2: Find distance of point from the line.
Distance of $P(2,3)$ from $x+y-6=0$ is
\[
D=\frac{|2+3-6|}{\sqrt{1^2+1^2}}=\frac{1}{\sqrt2}
\]
Step 3: Substitute values.
\[
\sin\frac{\theta}{2}
=\frac{\sqrt{\frac{2}{3}}}{\frac{1}{\sqrt2}}
=\sqrt{\frac{4}{3}}
=\frac{2}{\sqrt3}
\]
\[
\Rightarrow \sin\frac{\theta}{2}=\frac{\sqrt3}{2}
\]
Step 4: Find $\theta$.
\[
\frac{\theta}{2}=\frac{\pi}{6}
\Rightarrow \theta=\frac{\pi}{3}
\]
Final conclusion.
The angle between the two lines is $\dfrac{\pi}{3}$.