Step 1: The equation of the directrix is given as \( \sqrt{5}x = 4 \), which simplifies to: \[ x = \frac{4}{\sqrt{5}}. \] The point \( (4, -2\sqrt{3}) \) lies on the hyperbola.
Step 2: For the hyperbola, the relationship between the point and the directrix is given by: \[ \frac{|x - x_{{directrix}}|}{e} = \sqrt{x^2 + y^2}, \] where \( (x, y) = (4, -2\sqrt{3}) \) is a point on the hyperbola and the directrix is \( x = \frac{4}{\sqrt{5}} \). The distance from the point \( (4, -2\sqrt{3}) \) to the directrix is: \[ {Distance} = |4 - \frac{4}{\sqrt{5}}| = \left| 4 - \frac{4}{\sqrt{5}} \right|. \] Step 3: Using the distance formula for the point \( (4, -2\sqrt{3}) \), the left-hand side of the equation becomes: \[ {Distance from origin} = \sqrt{4^2 + (-2\sqrt{3})^2} = \sqrt{16 + 12} = \sqrt{28} = 2\sqrt{7}. \] Now, equating both sides: \[ \frac{|4 - \frac{4}{\sqrt{5}}|}{e} = 2\sqrt{7}. \] Step 4: Solving for \( e \), we get: \[ |4 - \frac{4}{\sqrt{5}}| = 4\left(1 - \frac{1}{\sqrt{5}}\right) = \frac{4(\sqrt{5} - 1)}{\sqrt{5}}. \] \[ e = \frac{\frac{4(\sqrt{5} - 1)}{\sqrt{5}}}{2\sqrt{7}} = \frac{\sqrt{5}}{\sqrt{2}} = \frac{\sqrt{10}}{2}. \] Finally, squaring \( e \): \[ e^2 = \left(\frac{\sqrt{10}}{2}\right)^2 = \frac{10}{4} = \frac{7}{2}. \]
A solid is dissolved in 1 L water. The enthalpy of its solution (\(\Delta H_{{sol}}^\circ\)) is 'x' kJ/mol. The hydration enthalpy (\(\Delta H_{{hyd}}^\circ\)) for the same reaction is 'y' kJ/mol. What is lattice enthalpy (\(\Delta H_{{lattice}}^\circ\)) of the solid in kJ/mol?