Step 1: Understand the concept of electronegativity.
Electronegativity is the tendency of an atom to attract shared electrons in a chemical bond.
It generally increases across a period (left to right) and decreases down a group (top to bottom) in the periodic table.
Step 2: Identify the element with the highest electronegativity.
- Fluorine (F) is the most electronegative element with a value of approximately 3.98 on the Pauling scale.
Step 3: Identify the element with the lowest electronegativity.
- Francium (Fr), an alkali metal at the bottom of Group 1, has the lowest electronegativity (estimated around 0.7).
Step 4: Conclusion.
The pair of elements with the highest and lowest electronegativity are Fluorine (F) and Francium (Fr) respectively.
Hence, the correct answer is: F and Fr.