Phosphorus (P) has the electronic configuration \( 1s^2 2s^2 2p^6 3s^2 3p^3 \), so it has 4 s-electrons and 3 p-electrons.
Calcium (Ca) has the electronic configuration \( 1s^2 2s^2 2p^6 3s^2 3p^6 4s^2 \), so it has 6 s-electrons and 6 p-electrons.
The ratio of s-electrons to p-electrons for the pair (P, Ca) is 2:3, making it the correct answer.