Step 1: Understanding Autocatalysis
Autocatalysis is a reaction where one of the products acts as a catalyst for the same reaction, thereby increasing its rate.
Step 2: Examining the Given Reactions Among the given reactions:
- Reaction (1) is the Haber process, catalyzed by iron and molybdenum, but not autocatalytic.
- Reaction (2) is the decomposition of potassium chlorate, catalyzed by manganese dioxide, not autocatalytic.
- Reaction (3) is hydrolysis of ethyl acetate, where the acetic acid (\( CH_3COOH \)) formed catalyzes further hydrolysis.
- Reaction (4) is a simple precipitation reaction and not autocatalytic.
Step 3: Conclusion Since acetic acid acts as a catalyst in the hydrolysis reaction, it is an example of an autocatalytic reaction.
At 298 K, for a first order reaction (A → P) the following graph is obtained. The rate constant (in s\(^{-1}\)) and initial concentration (in mol L\(^{-1}\)) of ‘A’ are respectively: