Question:

How many isomers of monobromoderivatives are obtained on bromination of the following compound ?

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Number of monohalogen derivatives equals the number of nonequivalent hydrogen atoms in the molecule.
Updated On: Feb 2, 2026
  • $4$
  • $3$
  • $2$
  • $5$
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The Correct Option is A

Solution and Explanation

Step 1: Identify the given hydrocarbon.
The given structure represents isopentane (2-methylbutane). It contains different types of hydrogen atoms due to its branched structure.

Step 2: Identify distinct hydrogen positions.
In isopentane, there are four nonequivalent types of hydrogen atoms:
Primary hydrogens at two different positions, secondary hydrogen, and tertiary hydrogen.

Step 3: Effect of bromination.
During monobromination, bromine can substitute hydrogen atoms at each nonequivalent position, leading to different structural isomers.

Step 4: Count of monobrominated products.
Since there are four different types of hydrogen atoms, four different monobromoderivatives are formed.

Step 5: Conclusion.
Therefore, the number of isomers of monobromoderivatives obtained is $4$.
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