Step 1: Understand the condition for a unique solution.
To determine when a system of linear equations has a unique solution, we need to check the condition on the determinant of the coefficient matrix. The system of equations given is:
\[
x - 2y = 3 \quad \text{(1)}
\]
\[
3x + my = 1 \quad \text{(2)}
\]
For a system to have a unique solution, the coefficient matrix:
\[
\begin{bmatrix}
1 & -2 \\
3 & m
\end{bmatrix}
\]
must have a non-zero determinant. The determinant \( D \) of a 2x2 matrix is given by:
\[
D = \begin{vmatrix}
1 & -2 \\
3 & m
\end{vmatrix}
\]
Step 2: Calculate the determinant.
The determinant of the matrix is:
\[
D = (1)(m) - (3)(-2) = m + 6
\]
Step 3: Set the condition for a unique solution.
For a unique solution to exist, the determinant must be non-zero:
\[
m + 6 \neq 0
\]
\[
m \neq -6
\]
Step 4: Conclusion.
Thus, for the pair of equations to have a unique solution, the value of \( m \) must not be \( -6 \). Therefore, the correct answer is (C).