For the reaction, A ⇌ B, Ea = 50 kJ mol−1 and ΔH = −20 kJ mol−1. When a catalyst is added, Ea decreases by 10 kJ mol−1. What is the Ea for the backward reaction in the presence of catalyst?
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The backward activation energy is calculated using E a,b=Ea,f−ΔH.
The backward activation energy is calculated as Ea,b=Ea,f−ΔH, giving Ea,b=40−(−20)=60kJ/mol when the catalyst reduces the forward activation energy to 40 kJ/mol.