For the matrices A and B, verify that (AB)′=B'A' where
I. A=\(\begin{bmatrix}1\\-4\\3\end{bmatrix}\),B=\(\begin{bmatrix}-1&2&1\end{bmatrix}\)
II. A= \(\begin{bmatrix}0\\1\\2\end{bmatrix}\),B=\(\begin{bmatrix}1&5&7\end{bmatrix}\)
I. A=\(\begin{bmatrix}1\\-4\\3\end{bmatrix}\),B=\(\begin{bmatrix}-1&2&1\end{bmatrix}\)
AB =\(\begin{bmatrix}1\\-4\\3\end{bmatrix}\)\(\begin{bmatrix}-1&2&1\end{bmatrix}\)
so (AB)'=\(\begin{bmatrix}-1&4&-3\\4&-8&6\\1&-4&3\end{bmatrix}\)
Now A'=\(\begin{bmatrix}-1&4&3\end{bmatrix}\),B'=\(\begin{bmatrix}-1\\2\\1\end{bmatrix}\)
so B'A'=\(\begin{bmatrix}-1&4&3\end{bmatrix}\)\(\begin{bmatrix}-1\\2\\1\end{bmatrix}\)
=\(\begin{bmatrix}-1&4&-3\\4&-8&6\\1&-4&3\end{bmatrix}\)
Hence we have verified that (AB)′=B'A'
II. A=\(\begin{bmatrix}0\\1\\2\end{bmatrix}\),B=\(\begin{bmatrix}1&5&7\end{bmatrix}\)
AB=\(\begin{bmatrix}0\\1\\2\end{bmatrix}\)\(\begin{bmatrix}1&5&7\end{bmatrix}\)=\(\begin{bmatrix}0&0&0\\1&5&7\\2&10&14\end{bmatrix}\)
so (AB)'=\(\begin{bmatrix}0&1&2\\0&5&10\\0&7&14\end{bmatrix}\)
Now A'=\(\begin{bmatrix}0&1&2\end{bmatrix}\),B'=\(\begin{bmatrix}1\\5\\7\end{bmatrix}\)
B'A'=\(\begin{bmatrix}1\\5\\7\end{bmatrix}\)\(\begin{bmatrix}0&1&2\end{bmatrix}\)=\(\begin{bmatrix}0&1&2\\0&5&10\\0&7&14\end{bmatrix}\)
Hence we have verified that (AB)′=B'A'
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.