Question:

For a chemical reaction A + B —q Product. the order is 1 with respect to A and B. What is the value of x and y?
Rate
mol L-1S-1
[A]
mol L-1
[B]
mol L-1
0.10200.5
0.40x0.5
0.8040y

Updated On: Jan 13, 2025
  • 80 and 4
  • 160 and 4
  • 40 and 4
  • 80 and 2
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The Correct Option is D

Solution and Explanation

Given: The reaction \( A + B \to \text{Product} \) is first order with respect to both \( A \) and \( B \). The rate law is:

\[ r = k[A][B] \]

where:

  • \( r \): Rate of the reaction
  • \( k \): Rate constant
  • \( [A] \) and \( [B] \): Concentrations of \( A \) and \( B \), respectively

Step 1: Set Up Equations

Using the given data, we can write the following equations:

  1. \( 0.10 = k(20)(0.5) \) — (1)
  2. \( 0.40 = k(x)(0.5) \) — (2)
  3. \( 0.80 = k(40)(Y) \) — (3)

Step 2: Solve for \( x \)

Divide equation (2) by equation (1):

\[ \frac{0.40}{0.10} = \frac{k(x)(0.5)}{k(20)(0.5)} \]

Simplify:

\[ 4 = \frac{x}{20} \quad \Rightarrow \quad x = 4 \times 20 = 80 \]

Step 3: Solve for \( Y \)

Divide equation (3) by equation (1):

\[ \frac{0.80}{0.10} = \frac{k(40)(Y)}{k(20)(0.5)} \]

Simplify:

\[ 8 = \frac{40Y}{10} \quad \Rightarrow \quad 80 = 40Y \quad \Rightarrow \quad Y = \frac{80}{40} = 2 \]

Final Answer:

The values of \( x \) and \( Y \) are 80 and 2, respectively.

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