Rate mol L-1S-1 | [A] mol L-1 | [B] mol L-1 |
0.10 | 20 | 0.5 |
0.40 | x | 0.5 |
0.80 | 40 | y |
\[ r = k[A][B] \]
where:
Using the given data, we can write the following equations:
Divide equation (2) by equation (1):
\[ \frac{0.40}{0.10} = \frac{k(x)(0.5)}{k(20)(0.5)} \]
Simplify:
\[ 4 = \frac{x}{20} \quad \Rightarrow \quad x = 4 \times 20 = 80 \]
Divide equation (3) by equation (1):
\[ \frac{0.80}{0.10} = \frac{k(40)(Y)}{k(20)(0.5)} \]
Simplify:
\[ 8 = \frac{40Y}{10} \quad \Rightarrow \quad 80 = 40Y \quad \Rightarrow \quad Y = \frac{80}{40} = 2 \]
The values of \( x \) and \( Y \) are 80 and 2, respectively.
Assertion (A): In a first order reaction, if the concentration of the reactant is doubled, its half-life is also doubled.
Reason (R): The half-life of a reaction does not depend upon the initial concentration of the reactant in a first order reaction.
If all the words with or without meaning made using all the letters of the word "KANPUR" are arranged as in a dictionary, then the word at 440th position in this arrangement is:
If the system of equations \[ x + 2y - 3z = 2, \quad 2x + \lambda y + 5z = 5, \quad 14x + 3y + \mu z = 33 \] has infinitely many solutions, then \( \lambda + \mu \) is equal to:}
The equilibrium constant for decomposition of $ H_2O $ (g) $ H_2O(g) \rightleftharpoons H_2(g) + \frac{1}{2} O_2(g) \quad (\Delta G^\circ = 92.34 \, \text{kJ mol}^{-1}) $ is $ 8.0 \times 10^{-3} $ at 2300 K and total pressure at equilibrium is 1 bar. Under this condition, the degree of dissociation ($ \alpha $) of water is _____ $\times 10^{-2}$ (nearest integer value). [Assume $ \alpha $ is negligible with respect to 1]