To find the values of \( a \) for which \( f(x) \) is decreasing, we first need to compute the derivative \( f'(x) \).
The derivative of \( f(x) \) is:
\[
f'(x) = \sqrt{3} \cos x + \sin x - 2a
\]
For \( f(x) \) to be decreasing on \( \mathbb{R} \), we need \( f'(x) \leq 0 \) for all \( x \).
The expression \( \sqrt{3} \cos x + \sin x \) is bounded, since it is the sum of sinusoidal functions. The maximum value occurs when:
\[
\sqrt{3} \cos x + \sin x = \sqrt{(\sqrt{3})^2 + 1^2} = 2
\]
Thus, we have the inequality:
\[
2 - 2a \leq 0
\]
Solving for \( a \), we get:
\[
a \leq 0
\]
Therefore, the values of \( a \) for which \( f(x) \) is decreasing are \( a \leq 0 \).