Answer When a die is tossed two times, we obtain (6 × 6) = 36 number of observations.
Let X be the random variable, which represents the number of successes.
i. Here, success refers to the number greater than 4.
P (X = 0) = P (number less than or equal to 4 on both the tosses) =\(\frac{2}{6}\times\frac{2}{6}=\frac{1}{9}\)
Thus, the probability distribution is as follows.
X | 0 | 1 | 2 |
P(X) | \(\frac{4}{9}\) | \(\frac{4}{9}\) | \(\frac{1}{9}\) |
(ii) Here, success means six appears on at least one die.
P (Y = 0) = P (six does not appear on any of the dice)=\(\frac{5}{6}\times\frac{5}{6}=\frac{25}{36}\)
P (Y = 1) = P (six appears on at least one of the dice) =\(\frac{11}{36}\)
Thus, the required probability distribution is as follows.
Y | 0 | 1 |
P(Y) | \(\frac{25}{36}\) | \(\frac{11}{36}\) |
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.