Step 1: Use the Taylor series expansions of \( e^x \), \( \log(1+x) \), and \( \sin x \) around \( x = 0 \) to simplify the expression: \[ e^x \approx 1 + x + \frac{x^2}{2}, \quad \log(1+x) \approx x - \frac{x^2}{2}, \quad \sin x \approx x - \frac{x^3}{6}. \] Step 2: Substitute these approximations into the limit: \[ \lim_{x \to 0} \frac{(1 + x + \frac{x^2}{2}) - a - (x - \frac{x^2}{2})}{x - \frac{x^3}{6}} = \lim_{x \to 0} \frac{1 - a + x^2}{x - \frac{x^3}{6}}. \] Step 3: For the limit to be zero, the numerator must not have a constant term other than zero when the denominator is approximated by \( x \), hence \( 1 - a = 0 \).
Step 4: Solving \( 1 - a = 0 \) gives \( a = 1 \).
A solid is dissolved in 1 L water. The enthalpy of its solution (\(\Delta H_{{sol}}^\circ\)) is 'x' kJ/mol. The hydration enthalpy (\(\Delta H_{{hyd}}^\circ\)) for the same reaction is 'y' kJ/mol. What is lattice enthalpy (\(\Delta H_{{lattice}}^\circ\)) of the solid in kJ/mol?