We are tasked with evaluating the integral: \[ I = \int \frac{dx}{x(x^4 + 1)}. \] To solve this, first notice the structure of the denominator, which suggests a decomposition or substitution.
Step 1: Perform a partial fraction decomposition. We decompose the fraction into two simpler fractions: \[ \frac{1}{x(x^4 + 1)} = \frac{A}{x} + \frac{Bx^3 + Cx}{x^4 + 1}. \] Multiplying through by \(x(x^4 + 1)\) to clear the denominator: \[ 1 = A(x^4 + 1) + (Bx^3 + Cx)x. \] This simplifies to: \[ 1 = A(x^4 + 1) + Bx^4 + Cx^2. \] Now, collect like terms: \[ 1 = (A + B)x^4 + Cx^2 + A. \] For this to hold for all \(x\), the coefficients of \(x^4\), \(x^2\), and the constant term must match. This gives the system of equations: \[ A + B = 0, \quad C = 0, \quad A = 1. \] Solving this system: \[ A = 1, \quad B = -1, \quad C = 0. \] Thus, we have: \[ \frac{1}{x(x^4 + 1)} = \frac{1}{x} - \frac{x^3}{x^4 + 1}. \] Step 2: Integrate each term separately. Now, the integral becomes: \[ I = \int \frac{1}{x} dx - \int \frac{x^3}{x^4 + 1} dx. \] - The first integral is straightforward: \[ \int \frac{1}{x} dx = \ln|x|. \] - For the second integral, use the substitution \( u = x^4 + 1 \), so \( du = 4x^3 dx \), or \( \frac{du}{4} = x^3 dx \): \[ \int \frac{x^3}{x^4 + 1} dx = \frac{1}{4} \int \frac{du}{u} = \frac{1}{4} \ln|u| = \frac{1}{4} \ln(x^4 + 1). \] Step 3: Combine the results. Thus, the total integral is: \[ I = \ln|x| - \frac{1}{4} \ln(x^4 + 1) + C. \] Step 4: Express the final answer. We can combine the logarithmic terms: \[ I = \frac{1}{4} \ln\left(\frac{x^4}{x^4 + 1}\right) + C. \] Thus, the correct answer is: \[ \boxed{\frac{1}{4} \log\left(\frac{x^4}{x^4 + 1}\right) + C}. \]
A solid is dissolved in 1 L water. The enthalpy of its solution (\(\Delta H_{{sol}}^\circ\)) is 'x' kJ/mol. The hydration enthalpy (\(\Delta H_{{hyd}}^\circ\)) for the same reaction is 'y' kJ/mol. What is lattice enthalpy (\(\Delta H_{{lattice}}^\circ\)) of the solid in kJ/mol?