Given that:
\[ P \propto T^3, \]
where \( P \) is the pressure and \( T \) is the absolute temperature.
Step 1: Using the Ideal Gas Law
From the ideal gas law, we have:
\[ \frac{PV}{T} = nR = \text{constant}. \]
Therefore:
\[ P \propto \frac{T}{V}. \]
Step 2: Relating Pressure and Temperature
Given that:
\[ P \propto T^3, \]
we can write:
\[ P = kT^3, \]
where \( k \) is a proportionality constant.
Step 3: Applying the Adiabatic Process Equation
For an adiabatic process, the relation is given by:
\[ PV^\gamma = \text{constant}, \]
where \( \gamma = \frac{C_P}{C_V} \) is the adiabatic index.
Step 4: Comparing the Relations
From the given proportionality:
\[ P \propto T^3 \quad \text{and} \quad P \propto V^{-\gamma}. \]
Equating the exponents:
\[ \gamma = 3. \]
Thus, the ratio of \( \frac{C_P}{C_V} \) is:
\[ \frac{C_P}{C_V} = \gamma = \frac{7}{5}. \]
Therefore, the correct answer is \( \frac{7}{5} \).
For a given reaction \( R \rightarrow P \), \( t_{1/2} \) is related to \([A_0]\) as given in the table. Given: \( \log 2 = 0.30 \). Which of the following is true?
\([A]\) (mol/L) | \(t_{1/2}\) (min) |
---|---|
0.100 | 200 |
0.025 | 100 |
A. The order of the reaction is \( \frac{1}{2} \).
B. If \( [A_0] \) is 1 M, then \( t_{1/2} \) is \( 200/\sqrt{10} \) min.
C. The order of the reaction changes to 1 if the concentration of reactant changes from 0.100 M to 0.500 M.
D. \( t_{1/2} \) is 800 min for \( [A_0] = 1.6 \) M.
Two vessels A and B are connected via stopcock. Vessel A is filled with a gas at a certain pressure. The entire assembly is immersed in water and allowed to come to thermal equilibrium with water. After opening the stopcock the gas from vessel A expands into vessel B and no change in temperature is observed in the thermometer. Which of the following statement is true?
Choose the correct nuclear process from the below options:
\( [ p : \text{proton}, n : \text{neutron}, e^- : \text{electron}, e^+ : \text{positron}, \nu : \text{neutrino}, \bar{\nu} : \text{antineutrino} ] \)
Let \( T_r \) be the \( r^{\text{th}} \) term of an A.P. If for some \( m \), \( T_m = \dfrac{1}{25} \), \( T_{25} = \dfrac{1}{20} \), and \( \displaystyle\sum_{r=1}^{25} T_r = 13 \), then \( 5m \displaystyle\sum_{r=m}^{2m} T_r \) is equal to: