Draw figure to show the splitting of d orbitals in an octahedral crystal field.
Solution and Explanation
The splitting of the d orbitals in an octahedral field takes palce in such a way that \(dx^2-y^2,dz^2\) , experience a rise in energy and form the \(e_g\) level, while \(dxy, dyz\) and \(dzx\) experience a fall in energy and form the \(t_{2g}\) level.
Top Questions on Coordination Compounds
The correct IUPAC name of \([ \text{Pt}(\text{NH}_3)_2\text{Cl}_2 ]^{2+} \) is:
- CBSE CLASS XII - 2025
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The Crystal Field Theory (CFT) of coordination compounds is based on the effect of different crystal fields (provided by the ligands taken as point charges) on the degeneracy of d-orbital energies of the central metal atom/ion. The splitting of the d-orbitals provides different electronic arrangements in strong and weak crystal fields. In tetrahedral coordination entity formation, the d-orbital splitting is smaller as compared to the octahedral entity.
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The Crystal Field Theory (CFT) of coordination compounds is based on the effect of different crystal fields (provided by the ligands taken as point charges) on the degeneracy of d-orbital energies of the central metal atom/ion. The splitting of the d-orbitals provides different electronic arrangements in strong and weak crystal fields. In tetrahedral coordination entity formation, the d-orbital splitting is smaller as compared to the octahedral entity.
On the basis of CFT, explain why [Ti(H$_2$O)$_6$]Cl$_3$ complex is coloured? What happens on heating the complex [Ti(H$_2$O)$_6$]Cl$_3$? Give reason.- CBSE CLASS XII - 2025
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Questions Asked in CBSE CLASS XII exam
- Differentiate: \[ \frac{\tan^{-1}\left(\frac{\sqrt{1 - x^2}}{x}\right)}{x} \quad \text{w.r.t.} \quad \cos^{-1}(2x\sqrt{1 - x^2}), \quad x \in \left(\frac{1}{\sqrt{2}}, 1\right) \]
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- Altima Ltd. invited applications for 2,00,000 equity shares of ₹ 10 at a premium of ₹ 4 per share. Amount payable:
On application and allotment – ₹ 7 (incl. ₹ 1 premium)
On first and final call – Balance.
Applications received for 2,40,000 shares. 30,000 rejected. Manvi allotted 4,000 shares failed to pay first and final call. Her shares were forfeited. These were reissued at ₹ 4 per share fully paid-up.
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Concepts Used:
Coordination Compounds
A coordination compound holds a central metal atom or ion surrounded by various oppositely charged ions or neutral molecules. These molecules or ions are re-bonded to the metal atom or ion by a coordinate bond.
Coordination entity:
A coordination entity composes of a central metal atom or ion bonded to a fixed number of ions or molecules.
Ligands:
A molecule, ion, or group which is bonded to the metal atom or ion in a complex or coordination compound by a coordinate bond is commonly called a ligand. It may be either neutral, positively, or negatively charged.