Step 1: Find the limit of \( f(x) \) as \( x \) approaches 0 from the left: \[ \lim_{x \to 0^-} f(x) = \lim_{x \to 0^-} \left( 1 + \frac{1 + \sin(|x|/\pi)}{x} \right). \] Using the series expansion of \( \sin x \) and considering the behavior around \( x = 0 \), this limit evaluates to 1.
Step 2: Find the limit of \( f(x) \) as \( x \) approaches 0 from the right: \[ \lim_{x \to 0^+} f(x) = \lim_{x \to 0^+} a \tan\left( \frac{2\pi x}{3} \right). \] Since \( \tan\left( \frac{2\pi x}{3} \right) \) near 0 approximates as \( \frac{2\pi x}{3} \), the limit becomes \( \frac{2\pi a}{3} \cdot 0 = 0 \). Set \( a = \frac{2}{3} \) for continuity.
Step 3: For continuity at \( x = 0 \), \( f(0) = b \) must equal the limits from both sides, which have been found to be 0. Thus, \( b = e^{\frac{2}{3}} \) ensures \( f(x) \) is continuous at \( x = 0 \).
A solid is dissolved in 1 L water. The enthalpy of its solution (\(\Delta H_{{sol}}^\circ\)) is 'x' kJ/mol. The hydration enthalpy (\(\Delta H_{{hyd}}^\circ\)) for the same reaction is 'y' kJ/mol. What is lattice enthalpy (\(\Delta H_{{lattice}}^\circ\)) of the solid in kJ/mol?