Step 1: Find the limit of \( f(x) \) as \( x \) approaches 0 from the left: \[ \lim_{x \to 0^-} f(x) = \lim_{x \to 0^-} \left( 1 + \frac{1 + \sin(|x|/\pi)}{x} \right). \] Using the series expansion of \( \sin x \) and considering the behavior around \( x = 0 \), this limit evaluates to 1.
Step 2: Find the limit of \( f(x) \) as \( x \) approaches 0 from the right: \[ \lim_{x \to 0^+} f(x) = \lim_{x \to 0^+} a \tan\left( \frac{2\pi x}{3} \right). \] Since \( \tan\left( \frac{2\pi x}{3} \right) \) near 0 approximates as \( \frac{2\pi x}{3} \), the limit becomes \( \frac{2\pi a}{3} \cdot 0 = 0 \). Set \( a = \frac{2}{3} \) for continuity.
Step 3: For continuity at \( x = 0 \), \( f(0) = b \) must equal the limits from both sides, which have been found to be 0. Thus, \( b = e^{\frac{2}{3}} \) ensures \( f(x) \) is continuous at \( x = 0 \).
Which of the following are ambident nucleophiles?
[A.] CN$^{\,-}$
[B.] CH$_{3}$COO$^{\,-}$
[C.] NO$_{2}^{\,-}$
[D.] CH$_{3}$O$^{\,-}$
[E.] NH$_{3}$
Identify the anomers from the following.

The standard Gibbs free energy change \( \Delta G^\circ \) of a cell reaction is \(-301 { kJ/mol}\). What is \( E^\circ \) in volts?
(Given: \( F = 96500 { C/mol}\), \( n = 2 \))