According to the generally accepted definition of the ideal solution there are equal interaction forces acting between molecules belonging to the same or different species. (This is equivalent to the statement that the activity of the components equals the concentration.) Strictly speaking, this concept is valid in ecological systems (isotopic mixtures of an element, hydrocarbons mixtures, etc.). It is still usual to talk about ideal solutions as limiting cases in reality since very dilute solutions behave ideally with respect to the solvent. This law is further supported by the fact that Raoult’s law empirically found for describing the behaviour of the solvent in dilute solutions can be deduced thermodynamically via the assumption of ideal behaviour of the solvent.
Answer the following questions:
(a) Give one example of miscible liquid pair which shows negative deviation from Raoult’s law. What is the reason for such deviation?
(b) (i) State Raoult’s law for a solution containing volatile components.
OR
(ii) Raoult’s law is a special case of Henry’s law. Comment.
(c) Write two characteristics of an ideal solution.
Sudha and Sudhir were partners in a firm sharing profits and losses in the ratio of 4 : 1. On 1st April, 2023, their fixed capitals were ₹12,00,000 and ₹4,00,000 respectively. On 1st July, 2023, Sudha invested ₹2,00,000 as additional capital. On 1st August, 2023, Sudhir withdrew ₹50,000 from his capital.
The partnership deed provided for the following:
(i) Interest on capital @ 6% p.a.
(ii) Interest on drawings @ 8% p.a.
During the year, Sudha withdrew ₹60,000 and Sudhir withdrew ₹40,000 for personal use. After providing interest on capital and charging interest on drawings, the net profit of the firm for the year ended 31st March, 2024 was ₹3,50,000.
Prepare Current Accounts of Sudha and Sudhir.
How do the peddler from ‘The Rattrap’ and ‘the office boy’ from ‘Poets and Pancakes’ compare in terms of their frustration, status, and grudges against others?
Show that the following lines intersect. Also, find their point of intersection:
Line 1: \[ \frac{x - 1}{2} = \frac{y - 2}{3} = \frac{z - 3}{4} \]
Line 2: \[ \frac{x - 4}{5} = \frac{y - 1}{2} = z \]