Question:

Coordination number of caesium in caesium chloride is

Updated On: May 12, 2024
  • 8
  • 6
  • 4
  • 12
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The Correct Option is A

Solution and Explanation

The coordination number of a molecule is referred to as the number of ions of the other charge surrounding the ion of the opposite charge. In the case of sodium chloride we have sodium ions placed and there are $6$ chloride ions surrounding each of the sodium ions. In the case of $NaCl$ the ratio is $1:1$ and as a result there are $6$ sodium ions surrounding the chloride ion and vice versa.
In case of the periodic table we are well aware that as we move down the group then the size of the cation increases and as a result of the increase in the number of the shell as we move down. Thus we find that the size of the ion increases and hence caesium has a very large size compared to that of sodium. Hence there is a change in structure: the cesium ions do not form a lattice similar to that of sodium but rather we find that it occupies the centre of the cube that there are $8$ chloride ions surrounding it. Also as the ratio of $CsCl$ is also as that of sodium hence we find that the coordination number remains as $8$ in this case.
Hence the answer to this question is that the coordination number of cesium in cesium chloride is $8$.
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Concepts Used:

Solid State

Solids are substances that are featured by a definite shape, volume, and high density. In the solid-state, the composed particles are arranged in several manners. Solid-state, in simple terms, means "no moving parts." Thus solid-state electronic devices are the ones inclusive of solid components that don’t change their position. Solid is a state of matter where the composed particles are arranged close to each other. The composed particles can be either atoms, molecules, or ions. 

Solid State

Types of Solids:

Based on the nature of the order that is present in the arrangement of their constituent particles solids can be divided into two types;

  • Amorphous solids behave the same as super cool liquids due to the arrangement of constituent particles in short-range order. They are isotropic and have a broad melting point (range is about greater than 5°C).
  • Crystalline solids have a fixed shape and the constituent particles are arranged in a long-range order.