1. Gauss's Law:
According to Gauss's Law, the electric field outside a spherical shell (where the radius is larger than the shell's radius) depends only on the net charge enclosed within the shell. The electric field at a distance \( r \) from the center of a spherical shell with total charge \( Q \) is given by:
\[ E = \frac{kQ}{r^2} \]
Where:
2. Charge Distribution:
Each shell consists of two charges:
To calculate the electric field outside each spherical shell at a distance \( 3R \), we will only consider the total charge enclosed by the outer shell. The charge on the inner concentric metal ball does not contribute to the electric field outside the shell because the electric field inside a conducting shell is zero.
3. Total Charge on Each Shell:
Thus, the net charge on all three shells is \( 4q \).
4. Electric Field at a Distance \( 3R \):
The electric field at a distance \( 3R \) from the center of each shell is given by:
\[ E = \frac{k \cdot 4q}{(3R)^2} = \frac{k \cdot 4q}{9R^2} \]
5. Conclusion:
Since the net charge on each shell is the same and the electric field depends only on the net charge enclosed within the spherical shell, the electric field at a distance \( 3R \) from the center of all three shells (A, B, and C) will be the same.
(a) Calculate the standard Gibbs energy (\(\Delta G^\circ\)) of the following reaction at 25°C:
\(\text{Au(s) + Ca\(^{2+}\)(1M) $\rightarrow$ Au\(^{3+}\)(1M) + Ca(s)} \)
\(\text{E\(^\circ_{\text{Au}^{3+}/\text{Au}} = +1.5 V, E\)\(^\circ_{\text{Ca}^{2+}/\text{Ca}} = -2.87 V\)}\)
\(\text{1 F} = 96500 C mol^{-1}\)
Define the following:
(i) Cell potential
(ii) Fuel Cell
Calculate the emf of the following cell at 25°C:
\[ \text{Zn(s)} | \text{Zn}^{2+}(0.1M) || \text{Cd}^{2+}(0.01M) | \text{Cd(s)} \] Given: \[ E^\circ_{\text{Cd}^{2+}/\text{Cd}} = -0.40 \, V, \, E^\circ_{\text{Zn}^{2+}/\text{Zn}} = -0.76 \, V \] \[ [\log 10 = 1] \]