Consider the reaction \(Cu^{2+} + X^- → Cu_2X_2 + X_2\).
X2 will be predominantly?
X2 will be predominantly?
- Cl2
- Br2
- I2
- All halogens are possible.
The Correct Option is C
Solution and Explanation
Top Questions on d -and f -Block Elements
- At temperature \(T\) K, \(2\) moles of liquid \(A\) and \(3\) moles of liquid \(B\) are mixed. The vapour pressure of the ideal solution formed is \(320\) mm Hg. At this stage, one mole of \(A\) and one mole of \(B\) are added to the solution. The vapour pressure is now measured as \(328.6\) mm Hg. The vapour pressures (in mm Hg) of pure \(A\) and pure \(B\) respectively are:
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- Consider the general reaction given below at 400 K: xA(g) ⇌ yB(g). The values of K___p and K___c are studied under the same condition of temperature but variation in x and y.
(i) K___p = 85.87 and K___c = 2.586
(ii) K___p = 0.862 and K___c = 28.62.
The values of x and y in (i) and (ii) respectively are :- JEE Main - 2026
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- d -and f -Block Elements
- Among the following oxides of 3d elements, the number of mixed oxides are ____________.
\[ \mathrm{Ti_2O_3,\ V_2O_4,\ Cr_2O_3,\ Mn_3O_4,\ Fe_3O_4,\ Fe_2O_3,\ Co_3O_4} \]- JEE Main - 2026
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- Statement-I : Consider the following pairs of ions $(\text{Sc}^{3+}, \text{Ti}^{3+}), (\text{Ti}^{4+}, \text{Ni}^{2+}), (\text{Cu}^{2+}, \text{Zn}^{2+})$ and $(\text{Cr}^{3+}, \text{Mn}^{3+})$. Out of these pairs three pairs consist of ions that are both coloured :
Statement-II : Among the lanthanide ions $\text{Eu}^{2+}$, $\text{Gd}^{3+}$, $\text{Ce}^{4+}$ and $\text{Tb}^{4+}$, the ion $\text{Tb}^{4+}$ is the strongest reducing agent.
Choose the correct option.- JEE Main - 2026
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- d -and f -Block Elements
- Why is the ability of oxygen greater than fluorine to stabilise higher oxidation states of transition metals?
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Questions Asked in JEE Main exam
In the given figure, the blocks $A$, $B$ and $C$ weigh $4\,\text{kg}$, $6\,\text{kg}$ and $8\,\text{kg}$ respectively. The coefficient of sliding friction between any two surfaces is $0.5$. The force $\vec{F}$ required to slide the block $C$ with constant speed is ___ N.
(Given: $g = 10\,\text{m s}^{-2}$)
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Two circular discs of radius \(10\) cm each are joined at their centres by a rod, as shown in the figure. The length of the rod is \(30\) cm and its mass is \(600\) g. The mass of each disc is also \(600\) g. If the applied torque between the two discs is \(43\times10^{-7}\) dyne·cm, then the angular acceleration of the system about the given axis \(AB\) is ________ rad s\(^{-2}\).
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- If \[ \frac{\tan(A-B)}{\tan A}+\frac{\sin^2 C}{\sin^2 A}=1, \quad A,B,C\in\left(0,\frac{\pi}{2}\right), \] then:
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Match the LIST-I with LIST-II for an isothermal process of an ideal gas system.
Choose the correct answer from the options given below:
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- A bag contains 10 balls out of which \( k \) are red and \( (10-k) \) are black, where \( 0 \le k \le 10 \). If three balls are drawn at random without replacement and all of them are found to be black, then the probability that the bag contains 1 red and 9 black balls is:
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Concepts Used:
d block elements
The elements, in the columns of the periodic table in which d subshells are being occupied are known as d block elements.
These are the elements that have the capability of forming stable cations with incompletely filled d orbitals. Elements like mercury and Zinc are not considered transition metals because they have electronic configurations: (n-1)d10 ns2. These elements have filled d-orbitals in their ground state and, therefore, even in some of their oxidation states.
General Properties Of d-Block Elements
- Multiple oxidation states- The oxidation states of d block elements show very few energy gaps; therefore, they exhibit many oxidation states. Also, the energy difference between s and d orbital is very less. Therefore both the electrons are involved in ionic and covalent bond formation, which ultimately leads to multiple oxidation states.
- Formation of complex compounds- Ligands show a binding behaviour and can form so many stable complexes with the help of transition metals. This property is mainly due to:
- Availability of vacant d orbitals.
- Comparatively small sizes of metals.
- Hardness- Transition elements are tough and have high densities because of the presence of unpaired electrons.
- Melting and boiling points- Melting and boiling points of transition are very high. This is because of the presence of unpaired electrons and partially filled d orbitals. Because of these two things, they form strong bonds and therefore have high melting and boiling points.
- Atomic radii- The atomic and ionic radius of the transition elements decreases as we move from Group 3 to group 6. However, it remains the same between group 7 and group 10, and from group 11 to group 12 increases.
- Ionization enthalpy- The ionization enthalpies of the transition elements are generally on the greater side as compared to the S block elements