The reaction of cyclohexane with potassium permanganate (\(\text{KMnO}_4\)) in an acidic medium (\(\text{H}_2\text{SO}_4\)) and heat results in the oxidation of cyclohexane to adipic acid.
Step 1: Oxidation of cyclohexane
Cyclohexane (\(\text{C}_6\text{H}_{12}\)) undergoes oxidation in the presence of \(\text{KMnO}_4\) and \(\text{H}_2\text{SO}_4\).
- The \(\text{KMnO}_4\) oxidizes the \(-\text{CH}_2-\) groups in cyclohexane to carboxylic acid (\(-\text{COOH}\)) groups.
- This results in the formation of adipic acid (\(\text{HOOC} - (\text{CH}_2)_4 - \text{COOH}\)).
\[\text{C}_6\text{H}_{12} \rightarrow [\text{KMnO}_4, \text{H}_2\text{SO}_4, \text{Heat}] \text{HOOC} - (\text{CH}_2)_4 - \text{COOH} \, (\text{Adipic Acid})\]
Step 2: Conclusion
The product \(A\) is adipic acid.
Final Answer: (4).
Consider the gas phase reaction: \[ CO + \frac{1}{2} O_2 \rightleftharpoons CO_2 \] At equilibrium for a particular temperature, the partial pressures of \( CO \), \( O_2 \), and \( CO_2 \) are found to be \( 10^{-6} \, {atm} \), \( 10^{-6} \, {atm} \), and \( 16 \, {atm} \), respectively. The equilibrium constant for the reaction is ......... \( \times 10^{10} \) (rounded off to one decimal place).
Molten steel at 1900 K having dissolved hydrogen needs to be vacuum degassed. The equilibrium partial pressure of hydrogen to be maintained to achieve 1 ppm (mass basis) of dissolved hydrogen is ......... Torr (rounded off to two decimal places). Given: For the hydrogen dissolution reaction in molten steel \( \left( \frac{1}{2} {H}_2(g) = [{H}] \right) \), the equilibrium constant (expressed in terms of ppm of dissolved H) is: \[ \log_{10} K_{eq} = \frac{1900}{T} + 2.4 \] 1 atm = 760 Torr.