Question:

Consider the following reaction:
benzyl alcohol (C6H5CH2OH)
The major product obtained is:

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When reacting alcohols with thionyl chloride (SOCl\(_2\)), the hydroxyl group is replaced by a chlorine atom, forming an alkyl chloride. This reaction typically proceeds via nucleophilic substitution (S\(_N\)2 mechanism) with the elimination of sulfur dioxide (SO\(_2\)) and hydrogen chloride (HCl).
Updated On: Feb 17, 2025
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The Correct Option is B

Solution and Explanation

When benzyl alcohol (C\(_6\)H\(_5\)CH\(_2\)OH) reacts with thionyl chloride (SOCl\(_2\)), the hydroxyl group (OH) is replaced by a chlorine atom, resulting in the formation of benzyl chloride (C\(_6\)H\(_5\)CH\(_2\)Cl). This is a typical reaction for alcohols with SOCl\(_2\), where the alcohol undergoes nucleophilic substitution. Thus, the major product is benzyl chloride (C\(_6\)H\(_5\)CH\(_2\)Cl).
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