Question:

Consider an electron moving in the first Bohr orbit of a He\(^+\) ion with velocity \(v_1\). If it is allowed to move in the third Bohr orbit with velocity \(v_3\), determine the correct \(v_3 : v_1\) ratio.\\

Updated On: Apr 3, 2025
  • 3:1
  • 2:1
  • 1:3
  • 1:2
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The Correct Option is C

Approach Solution - 1

The velocity of an electron in a Bohr orbit is inversely proportional to the principal quantum number (n):

\( v \propto \frac{1}{n} \)

For the first Bohr orbit (n=1), the velocity is \(v_1\). For the third Bohr orbit (n=3), the velocity is \(v_3\). Using the proportionality:

\( \frac{v_3}{v_1} = \frac{1/3}{1/1} = \frac{1}{3} \)

Thus, the ratio \(v_3 : v_1\) is 1:3.

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Approach Solution -2

Option 3: 1:3

Explanation:

1. Bohr's Velocity Equation:

v = (Z * e2) / (2 * ε0 * h * n)

where:

  • v = velocity
  • Z = atomic number
  • e = elementary charge
  • ε0 = permittivity of free space
  • h = Planck's constant
  • n = principal quantum number

2. Velocity in the First Bohr Orbit (v1):

For He+, Z = 2 and n = 1.

v1 = (2 * e2) / (2 * ε0 * h * 1) = e2 / (ε0 * h)

3. Velocity in the Third Bohr Orbit (v3):

For He+, Z = 2 and n = 3.

v3 = (2 * e2) / (2 * ε0 * h * 3) = e2 / (3 * ε0 * h)

4. Determine the v3:v1 Ratio:

v3 / v1 = [e2 / (3 * ε0 * h)] / [e2 / (ε0 * h)] = 1/3

Therefore, v3 : v1 = 1 : 3

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