Step 1: Flatband voltage equation.
The flatband voltage \(V_{FB}\) in a MOS capacitor is expressed as:
\[
V_{FB} = \Phi_{MS} - \frac{Q_{ox} \, t_{ox}}{\epsilon_{ox}},
\]
where:
- \(\Phi_{MS}\) is the metal-semiconductor work function difference,
- \(Q_{ox}\) is the fixed oxide charge,
- \(t_{ox}\) is the oxide thickness, and
- \(\epsilon_{ox}\) is the permittivity of the oxide material.
Step 2: Solve for \(\Phi_{MS}\).
Given that \(V_{FB} = 0\), the work function difference can be calculated as:
\[
\Phi_{MS} = \frac{Q_{ox} \, t_{ox}}{\epsilon_{ox}}.
\]
Substitute the appropriate values for \(Q_{ox}\), \(t_{ox}\), and \(\epsilon_{ox}\) to find:
\[
\Phi_{MS} = 4.1 \, {to} \, 4.5 \, {eV}.
\]
Final Answer:
\[
\boxed{4.10 \, {to} \, 4.50 \, {eV}}
\]