The correct relationship between GPP, R, and NPP is:
\[
\text{GPP} - \text{R} = \text{NPP}
\]
Where:
- GPP is the total energy captured by producers in an ecosystem.
- R is the energy used by producers for respiration.
- NPP is the energy left after respiration and available for growth.
Conclusion:
The correct answer is (4) GPP - R = NPP.
Final Answer:
\[
\boxed{\text{The correct equation is GPP - R = NPP.}}
\]