By using properties of determinants, show that: \(\begin{vmatrix}-a^2&ab&ac\\ba&-b^2&bc\\ca&cb&-c^2\end{vmatrix}\)=4a2b2c2
△=\(\begin{vmatrix}-a^2&ab&ac\\ba&-b^2&bc\\ca&cb&-c^2\end{vmatrix}\)
=\(abc\begin{vmatrix}-a&b&c\\a&-b&c\\a&b&-c\end{vmatrix}\) [Taking out factors a,b,c from R1,R2and R3]
=a2b2c2 \(\begin{vmatrix}-1&1&1\\1&-1&1\\1&1&-1\end{vmatrix}\) [Taking out factors a,b,c from C1,C2and C3]
Applying R2 → R2 + R1 and R3 → R3 + R1, we have:
△=a2b2c2\(\begin{vmatrix}-1&1&1\\0&0&2\\0&2&0\end{vmatrix}\)
=a2b2c2(-1)\(\begin{vmatrix}0&2\\2&0\end{vmatrix}\)
=-a2b2c2(0-4)
=4a2b2c2
(a) State the following:
(i) Kohlrausch law of independent migration of ions
A solution of glucose (molar mass = 180 g mol\(^{-1}\)) in water has a boiling point of 100.20°C. Calculate the freezing point of the same solution. Molal constants for water \(K_f\) and \(K_b\) are 1.86 K kg mol\(^{-1}\) and 0.512 K kg mol\(^{-1}\) respectively.
Write the reactions involved when D-glucose is treated with the following reagents: (a) HCN (b) Br\(_2\) water
Identify A and B in each of the following reaction sequence:
(a) \[ CH_3CH_2Cl \xrightarrow{NaCN} A \xrightarrow{H_2/Ni} B \]
(b) \[ C_6H_5NH_2 \xrightarrow{NaNO_2/HCl} A \xrightarrow{C_6H_5NH_2} B \]
Would you expect benzaldehyde to be more reactive or less reactive in nucleophilic addition reactions than propanal? Justify your answer.
Read More: Properties of Determinants